INSERTION OF CARBON-MONOXIDE INTO ALLYLIC CARBON-SULFUR BONDS CATALYZED BY PALLADIUM AND RUTHENIUM COMPLEXES

被引：31

作者：

CRUDDEN, CM ^{[1
]}

ALPER, H ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 17期

关键词：

D O I：

10.1021/jo00122a045

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The metal complex-catalyzed insertion of carbon monoxide into the C-S bond of various allylic sulfides affords thioesters in up to 88% yield. The reaction is catalyzed by various palladium complexes, with concomitant isomerization of the olefin into conjugation with the carbonyl group. In these cases, only the trans isomer was detected by H-1 NMR spectroscopy. Ruthenium complexes also catalyzed the carbonylation but the initially formed beta,gamma-thioester was not isomerized.

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页码：5579 / 5587

页数：9

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