HPLC-SCREENING METHOD FOR THE DETERMINATION OF THE ADSORPTION-COEFFICIENT ON SOIL - RESULTS OF A RING-TEST

被引:22
作者
KORDEL, W
KOTTHOFF, G
MULLER, J
机构
[1] Fraunhofer-Institut für Umweltchemie and Ökotoxikologie
关键词
D O I
10.1016/0045-6535(95)00030-C
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A HPLC-screening method is proposed for the determination of the adsorption-coefficient on soil satisfying the requirements of the base set in the updated chemicals notification scheme. Before adopting the HPLC-screening method a validation by means of a ring test had to be performed. The results of the ring test with 11 participating laboratories showed that the HPLC-screening method can easily be performed in any analytical laboratory producing matrix independent PC-data of high precision. The standard deviations obtained in the ring test using the screening method are smaller than deviations normally achieved with the adsorption/desorption test according to guideline No 106 using different soils.
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页码:1373 / 1384
页数:12
相关论文
共 25 条
[21]  
PIGNATELLO JJ, 1989, SSSA SPECIAL PUBLICA, V22, P45
[22]   A REVIEW OF METHODS FOR THE DETERMINATION OF HOLD-UP VOLUME IN MODERN LIQUID-CHROMATOGRAPHY [J].
SMITH, RJ ;
NIEASS, CS ;
WAINWRIGHT, MS .
JOURNAL OF LIQUID CHROMATOGRAPHY, 1986, 9 (07) :1387-1430
[23]   DETERMINATION OF THE ADSORPTION COEFFICIENT (KOC) OF SOME AROMATICS FOR SOIL BY RP-HPLC ON 2 IMMOBILIZED HUMIC-ACID PHASES [J].
SZABO, G ;
PROSSER, SL ;
BULMAN, RA .
CHEMOSPHERE, 1990, 21 (06) :777-788
[24]  
VANOEPEN B, 1991, CHEMOSPHERE, V22, P285
[25]  
DIN38402 42