PALLADIUM-CATALYZED INSERTION OF NORBORNENES AND ETHYLENE INTO SILICON-TIN SIGMA-BONDS - SILYLSTANNATION OF ALKENES WITH SILYLSTANNANES

被引：27

作者：

OBORA, Y ^{[1
]}

TSUJI, Y ^{[1
]}

ASAYAMA, M ^{[1
]}

KAWAMURA, T ^{[1
]}

机构：

[1] GIFU UNIV,FAC ENGN,DEPT CHEM,GIFU 50111,JAPAN

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 11期

关键词：

D O I：

10.1021/om00035a069

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Organosilylstannanes 1 react with norbornene (2a), benzonorbornadiene (2b), and ethylene (2c) at 130-degrees-C in the presence of a catalytic amount of bis(dibenzylideneacetone)palladium combined with a trialkylphosphine to afford silylstannation products 3 in high yields.

引用

收藏

页码：4697 / 4699

页数：3

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