PD(O)-CATALYZED ELIMINATION AND COUPLING OF ALLYLIC CYCLIC CARBONATES

被引：8

作者：

KANG, SK

PARK, DC

PARK, CH

HONG, RK

机构：

[1] Department of Chemistry, Sung Kyun Kwan University, Suwon, 440-746, Natural Science Campus

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 03期

关键词：

D O I：

10.1016/0040-4039(94)02220-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The alkyl substituted allylic cyclic carbonates 1a-d undergo elimination by using a catalytic amount of Pd(O) complex to form dienols 2a-b. However, on treatment of the unsubstituted or phenyl substituted allylic cyclic carbonates le and If with palladium(O) catalyst, deprotonation-elimination of pi-allylpalladium complex followed by condensation with the other pi-allylpalladium complex provided the coupled products 3a and 3b, respectively.

引用

页码：405 / 408

页数：4

共 6 条

[1] 1,4-BISMETHANESULFONATES OF STEREOISOMERIC BUTANETETRAOLS + RELATED COMPOUNDS [J].