UNIMOLECULAR REACTIONS IN A SPHERICALLY SYMMETRICAL POTENTIAL .3. LIFETIMES OF COLLISION COMPLEXES

被引：15

作者：

KLOTS, CE ^{[1
]}

POLACH, J ^{[1
]}

机构：

[1] ACAD SCI CZECH REPUBL,J HEYROVSKY INST PHYS CHEM & ELECTROCHEM,CR-18223 PRAGUE 8,CZECH REPUBLIC

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 42期

关键词：

D O I：

10.1021/j100042a011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We describe an analytical procedure for obtaining rate constants, branching ratios, and kinetic energy distributions following the unimolecular dissociation of a species with arbitrary energy and angular momentum. With it the effects of small changes in the assumed potential energy surface can be readily examined. Limitations to the Rice-Gershinowitz hypothesis concerning angular momentum effects are identified. It is further shown how angular momentum can affect a branching ratio and thus, indirectly, a kinetic energy distribution.

引用

页码：15396 / 15399

页数：4

共 15 条

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