SYNTHESIS AND STRUCTURE OF A DISULFIDO-BRIDGED MIXED-VALENT RU(II)RU(III) COMPLEX [(RU(AN)3(TMP)2)2(MU-S2)](PF6)3 (AN = ACETONITRILE, TMP = P (OME)3)

被引:16
作者
MATSUMOTO, T
MATSUMOTO, K
机构
关键词
D O I
10.1246/cl.1992.1539
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first structural analysis of a S-2(2-)-bridged Ru(II)Ru(III) compound is reported. The compound was isolated from an acetonitrile solution of [{RuCl(TMP)2}2(mu-Cl)2(mu-S2)] with the addition of NaPF6. The two Ru atoms are equivalent and are bridged by a S2(2-) ligand in trans positions.
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页码:1539 / 1542
页数:4
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