BIFURCATED BRIDGING CYANO GROUP AND NETWORK OF HYDROGEN-BONDED WATER-MOLECULES IN A NOVEL FRAMEWORK HOST INCLUSION COMPOUND TRIAQUACADMIUM(II) TRICYANOCUPRATE(I)-ACETONITRILE(1/1)

被引：15

作者：

NISHIKIORI, S

IWAMOTO, T

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 07期

关键词：

D O I：

10.1246/cl.1994.1199

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dimeric structure unit of [Cu-2(CN)(6)](4-) in the title inclusion compound involves two bifurcated CN groups respectively linked to two Cu(I) at the C and a Cd(II) at the N to form the framework host accommodating the CH3CN whose orientation is regulated with the hydrogen bonds among the guest and the waters of coordination in the host.

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页码：1199 / 1202

页数：4

相关论文

共 12 条

[1] CRYSTAL STRUCTURE OF CUCN.NH3 [J].

CROMER, DT ;

LARSON, AC ;

ROOF, RB .

ACTA CRYSTALLOGRAPHICA, 1965, 19 :192-&

[2] QUADRUPOLAR ECHO DEUTERON MAGNETIC-RESONANCE SPECTROSCOPY IN ORDERED HYDROCARBON CHAINS [J].

DAVIS, JH ;

JEFFREY, KR ;

BLOOM, M ;

VALIC, MI ;

HIGGS, TP .

CHEMICAL PHYSICS LETTERS, 1976, 42 (02) :390-394

[3] DESIGN AND CONSTRUCTION OF A NEW CLASS OF SCAFFOLDING-LIKE MATERIALS COMPRISING INFINITE POLYMERIC FRAMEWORKS OF 3-D-LINKED MOLECULAR RODS - A REAPPRAISAL OF THE ZN(CN)2 AND CD(CN)2 STRUCTURES AND THE SYNTHESIS AND STRUCTURE OF THE DIAMOND-RELATED FRAMEWORKS [N(CH3)4][CUIZNII(CN)4] AND CUI[4,4',4'',4'''-TETRACYANOTETRAPHENYLMETHANE]BF4.XC6H5NO2 [J].

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (04) :1546-1554

[4] GUEST-DEPENDENT [CD(CN)2]N HOST STRUCTURES OF CADMIUM CYANIDE ALCOHOL CLATHRATES - 2 NEW [CD(CN)2]N FRAMEWORKS FORMED WITH PRNOH AND PRIOH GUESTS [J].

KIM, J ;

WHANG, D ;

LEE, JI ;

KIM, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (18) :1400-1402

[5] TETRAHEDRAL GUEST IN A TETRAHEDRAL CAVITY - A NEOPENTANE MOLECULE ENCAGED IN A 3-DIMENSIONAL CADMIUM CYANIDE FRAMEWORK [J].

KITAZAWA, T ;

NISHIKIORI, S ;

YAMAGISHI, A ;

KURODA, R ;

IWAMOTO, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (05) :413-415

[6] STRUCTURAL CHARACTERIZATION OF INFINITE 3-DIMENSIONAL [CD4(CN)9]-ION [J].

KITAZAWA, T ;

SUGISAWA, H ;

TAKEDA, M ;

IWAMOTO, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (24) :1855-1856

[7]

KITAZAWA T, 1988, CHEM LETT, V459

[8]

KITAZAWA T, 1992, MATER SCI FORUM, V91, P257

[9] FRAMEWORK ORDERING IN SOLID CADMIUM CYANIDES FROM CD-113 NMR-SPECTROSCOPY [J].

NISHIKIORI, S ;

RATCLIFFE, CI ;

RIPMEESTER, JA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (10) :735-736

[10] CD-113 NMR-STUDIES OF HOFMANN-TYPE CLATHRATES AND RELATED-COMPOUNDS - EVIDENCE FOR 2 ROOM-TEMPERATURE ORIENTATIONAL GLASSES [J].

NISHIKIORI, S ;

RATCLIFFE, CI ;

RIPMEESTER, JA .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1990, 68 (12) :2270-2273