OCTAMERIC TITANIUM OXO METALLACYCLE WITH HOST-GUEST INTERACTIONS

被引：39

作者：

BARROW, H

BROWN, DA

ALCOCK, NW

CLASE, HJ

WALLBRIDGE, MGH

机构：

[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

[2] MEM UNIV NEWFOUNDLAND,DEPT CHEM,ST JOHNS,NF A1B 3X7,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 12期

关键词：

D O I：

10.1039/c39950001231

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of TiCl4 with carboxylic acids RCO(2)H (R = C6F5, CH2C6F5, CH2OC6F5) yields a series of titanium oxo compounds; the X-ray molecular structure of [TiO(O2CC6F5)(2)] reveals an octameric unit and a unique 16-membered Ti8O8 ring, with two toluene molecules encapsulated above and below the ring in the molecular cavity.

引用

页码：1231 / 1232

页数：2

共 15 条

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