BETA-SELECTIVE EPOXIDATION OF CHOLESTEROL DERIVATIVES WITH MOLECULAR-OXYGEN AND ALDEHYDE CATALYZED BY MANGANESE(II) COMPLEX

被引：63

作者：

YAMADA, T

IMAGAWA, K

MUKAIYAMA, T

机构：

来源：

CHEMISTRY LETTERS | 1992年 / 11期

关键词：

D O I：

10.1246/cl.1992.2109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a catalytic amount of bis(dipivaloylmethanato)manganese(II) (= Mn(dpm)2), various cholesterol derivatives are smoothly converted into the corresponding beta-epoxides in good to high yields with combined use of molecular oxygen and isobutyraldehyde. These stereoselectivities are the reversal of the cases using peracid such as mCPBA.

引用

页码：2109 / 2112

页数：4

共 11 条

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