REGIOSELECTIVE NUCLEOPHILIC RING-OPENING OF OXABICYCLIC COMPOUNDS

被引：23

作者：

LAUTENS, M

CHIU, P

机构：

[1] Department of Chemistry University of Toronto, Toronto

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 05期

关键词：

D O I：

10.1016/0040-4039(93)89008-E

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The ring opening of unsymmetrical oxabicyclic compounds was found to be highly regioselective, giving rise to products from the attack of the nucleophile distal to the bridgehead substituent. Ozonolysis furnished acyclic chains with up to five stereocenters and differentiated ends.

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页码：773 / 776

页数：4

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