GALLIUM DICHLORIDE-MEDIATED REDUCTIVE FRIEDEL-CRAFTS REACTION

被引：26

作者：

HASHIMOTO, Y ^{[1
]}

HIRATA, K ^{[1
]}

KAGOSHIMA, H ^{[1
]}

KIHARA, N ^{[1
]}

HASEGAWA, M ^{[1
]}

SAIGO, K ^{[1
]}

机构：

[1] UNIV TOKYO,FAC ENGN,DEPT SYNTHET CHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

TETRAHEDRON | 1993年 / 49卷 / 27期

关键词：

D O I：

10.1016/S0040-4020(01)87183-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of gallium dichloride, the reaction of carbonyl compounds or their dimethylacetals with aromatic compounds afforded Friedel-Crafts alkylated adducts in good yields. It was suggested that the adducts were obtained by way of a reduction of the carbonyl compounds or their dimethylacetals, followed by the Friedel-Crafts reaction in one-pot. This is the first organic synthetic method with gallium dichloride, low valent gallium.

引用

页码：5969 / 5978

页数：10

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