PREPARATION AND CHARACTERIZATION OF NEW SB-CONTAINING TERNARY SULFIDES WITH LAYERED COMPOSITE CRYSTAL-STRUCTURE

被引：16

作者：

GOTOH, Y ^{[1
]}

ONODA, M ^{[1
]}

AKIMOTO, J ^{[1
]}

OOSAWA, Y ^{[1
]}

机构：

[1] NATL INST RES INORGAN MAT, TSUKUBA, IBARAKI 305, JAPAN

来源：

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS | 1991年 / 30卷 / 6A期

关键词：

NEW TERNARY SULFIDE; COMPOSITE CRYSTAL; LAYERED STRUCTURE; ANTIMONY SULFIDE; DISULFIDE; INTERCALATION; ELECTRIC RESISTIVITY;

D O I：

10.1143/JJAP.30.L1039

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

New Sb-Containing ternary sulfides with layered composite crystal structure have been prepared and characterized: (SbS)(n)TiS2, (SbS)(n)TaS2, (SbS)n(NbS2)2, and (SbS)n(TaS2)2; n congruent-to 1. On the basis of X-ray and electron diffraction patterns, it is suggested that the first and the second sulfides consist of a SbS and a TS2 (T = Ti or Ta) layers stacked alternately and that the third and the fourth sulfides consist of a SbS and two TS2 (T = Nb or Ta) layers stacked alternately. The in-plane electric resistivity of (SbS)(n)TaS2 showed metallic temperature dependence in the region of 4.2-300 K.

引用

收藏

页码：L1039 / L1041

页数：3

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