PHASE-BEHAVIOR OF BLENDS OF POLY(ACETONYL METHACRYLATE) WITH POLY(STYRENE-CO-ACRYLONITRILE) AND POLY(PARA-METHYLSTYRENE-CO-ACRYLONITRILE)

被引：2

作者：

CHONG, YF ^{[1
]}

GOH, SH ^{[1
]}

机构：

[1] NATL UNIV SINGAPORE, DEPT CHEM, SINGAPORE 0511, SINGAPORE

来源：

POLYMER | 1992年 / 33卷 / 06期

关键词：

BLENDS; PHASE BEHAVIOR; POLY(ACETONYL METHACRYLATE); LOWER CRITICAL SOLUTION TEMPERATURE; SOLUBILITY PARAMETER;

D O I：

10.1016/0032-3861(92)90776-S

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The miscibility of poly(acetonyl methacrylate) (PACMA) with poly(styrene-co-acrylonitrile) (SAN) and poly(p-methylstyrene-co-acrylonitrile) (pMSAN) has been studied by differential scanning calorimetry. PACMA is miscible with SAN having acrylonitrile (AN) contents between 33 wt% and 58 wt% and with pMSAN having AN contents between 43 wt% and 61 wt%. Three segmental interaction parameters, chi(ACMA/S), chi(ACMA/pMS) and chi(ACMA/AN), were found to be 0.15, 0.22 and 0.24, respectively. The results obtained for PACMA are compared to those of poly(n-propyl methacrylate) and poly(isopropyl methacrylate). The miscibility behaviour is discussed in terms of the binary interaction model as well as the non-hydrogen-bonded solubility parameter concept.

引用

页码：1289 / 1292

页数：4

共 20 条

[1] MISCIBILITY OF POLY(ACETONYL METHACRYLATE) WITH SOME CHLORINE-CONTAINING POLYMERS [J].

CHONG, YF ;

LEE, SY ;

GOH, SH .

EUROPEAN POLYMER JOURNAL, 1990, 26 (11) :1207-1210

[2] MISCIBILITY OF POLY(ACETONYL METHACRYLATE) AND POLY(NORMAL-PROPYL METHACRYLATE) WITH POLY(VINYLIDENE FLUORIDE) [J].

CHONG, YF ;

LEE, SY ;

GOH, SH .

EUROPEAN POLYMER JOURNAL, 1990, 26 (10) :1145-1147

[3]

CHONG YF, IN PRESS POLYMER

[4] A PRACTICAL GUIDE TO POLYMER MISCIBILITY [J].

COLEMAN, MM ;

SERMAN, CJ ;

BHAGWAGAR, DE ;

PAINTER, PC .

POLYMER, 1990, 31 (07) :1187-1203

[5] MISCIBILITY MAPPING IN SOME BLENDS INVOLVING POLY(STYRENE-CO-ACRYLONITRILE) [J].

COWIE, JMG ;

LATH, D .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1988, 16 :103-112

[6] PREDICTIONS OF THE MISCIBILITY BEHAVIOR OF COPOLYMER BLENDS INVOLVING THE MONOMERS N-PHENYLITACONIMIDE, METHYL-METHACRYLATE, STYRENE AND ACRYLONITRILE [J].

COWIE, JMG ;

REID, VMC ;

MCEWEN, IJ .

POLYMER, 1990, 31 (05) :905-908

[7] PREDICTION OF THE MISCIBILITY RANGE IN BLENDS OF POLY(STYRENE-CO-ACRYLONITRILE) AND POLY(N-PHENYL ITACONIMIDE-CO-METHYL METHACRYLATE) - A 6-INTERACTION-PARAMETER SYSTEM [J].

COWIE, JMG ;

REID, VMC ;

MCEWEN, IJ .

POLYMER, 1990, 31 (03) :486-489

[8] EFFECT OF COPOLYMER COMPOSITION ON THE MISCIBILITY OF BLENDS OF STYRENE ACRYLONITRILE COPOLYMERS WITH POLY(METHYL METHACRYLATE) [J].

FOWLER, ME ;

BARLOW, JW ;

PAUL, DR .

POLYMER, 1987, 28 (07) :1177-1184

[9] MISCIBILITY OF BROMOBENZYLATED POLY(2,6-DIMETHYL-1,4-PHENYLENE OXIDE) WITH POLY(PARA-METHYLSTYRENE) [J].

GOH, SH ;

LEE, SY .

EUROPEAN POLYMER JOURNAL, 1989, 25 (06) :571-573

[10] MISCIBILITY OF POLY(CHLOROMETHYL METHACRYLATE) WITH POLY(STYRENE-CO-ACRYLONITRILE) [J].

GOH, SH ;

LEE, SY .

JOURNAL OF APPLIED POLYMER SCIENCE, 1990, 41 (7-8) :1391-1394

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