SILASESQUIOXANES AS LIGANDS IN INORGANIC AND ORGANOMETALLIC CHEMISTRY

被引：381

作者：

FEHER, FJ ^{[1
]}

BUDZICHOWSKI, TA ^{[1
]}

机构：

[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

来源：

POLYHEDRON | 1995年 / 14卷 / 22期

关键词：

D O I：

10.1016/0277-5387(95)85009-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silasesquioxanes are an interesting class of ligands for both main group and transition-metal elements. A variety of coordination environments can be supported by silasesquioxane ligands, and it is now possible to prepare metallasilsesquioxanes containing practically any stable element from Groups 1015. This article surveys the synthesis, characterization, and reactivity of silasesquioxane ligands. Structure, bonding and structural dynamics of both silasesquioxanes and metallasilasesquioxanes are also discussed. The chemistry of silasesquioxanes and metallasilasesquioxanes can provide important insights into the chemistry of silica and silica-supported transition-metal catalysts. The uniqueness of silasesquioxanes as models for silica is discussed and several systems which provide molecular-level insights into the surface chemistry of silica and silica-supported catalysts are discussed.

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收藏

页码：3239 / 3253

页数：15

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共 85 条

[31] NEW POLYHEDRAL OLIGOSILSESQUIOXANES VIA THE CATALYTIC-HYDROGENATION OF ARYL-CONTAINING SILSESQUIOXANES [J].

FEHER, FJ ;

BUDZICHOWSKI, TA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 373 (02) :153-163

[32] HETEROSILSESQUIOXANES - SYNTHESIS AND CHARACTERIZATION OF GROUP-15 CONTAINING POLYHEDRAL OLIGOSILSESQUIOXANES [J].

FEHER, FJ ;

BUDZICHOWSKI, TA .

ORGANOMETALLICS, 1991, 10 (03) :812-815

[33] ANTIFERROMAGNETIC EXCHANGE IN AN ISOMORPHOUS SERIES OF SILOXY-BRIDGED EARLY-TRANSITION-METAL DIMERS - COMPARISONS OF ANTIFERROMAGNETIC EXCHANGE INTERACTIONS IN ISOMORPHOUS D1-D1, D1-D2, D2-D2, AND D2-D3 EXCHANGE-COUPLED DIMERS [J].

FEHER, FJ ;

WALZER, JF .

INORGANIC CHEMISTRY, 1990, 29 (09) :1604-1611

[34] DIMERIC VERSUS MONOMERIC TITANIUM(III) SILOXIDE COMPLEXES - SYNTHESES AND CHARACTERIZATION OF [(C-C6H11)7(SI7O12)TIIII]2 AND [(C-C6H11)7(SI7O12)TIIII(C5H5N)]2 [J].

FEHER, FJ ;

GONZALES, SL ;

ZILLER, JW .

INORGANIC CHEMISTRY, 1988, 27 (20) :3440-3442

[35] OXIDE-BASE ADDUCTS OF ALUMINUM - X-RAY CRYSTAL-STRUCTURES OF ME3AL(OPPH3), ME3AL(ONME3) AND [(CH3)3SIO]3AL(OPPH3) [J].

FEHER, FJ ;

BUDZICHOWSKI, TA ;

WELLER, KJ .

POLYHEDRON, 1993, 12 (06) :591-599

[36] LEWIS ACID ADDUCTS OF OXOVANADIUM(V) ALKYL AND TRIPHENYLSILOXY COMPLEXES - SYNTHESIS, CHARACTERIZATION, AND REACTIVITY TOWARD ETHYLENE [J].

FEHER, FJ ;

BLANSKI, RL .

ORGANOMETALLICS, 1993, 12 (03) :958-963

[37] SYNTHESES OF HIGHLY-FUNCTIONALIZED POLYHEDRAL OLIGOSILSESQUIOXANES [J].

FEHER, FJ ;

BUDZICHOWSKI, TA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 379 (1-2) :33-40

[38] POLYHEDRAL ALUMINOSILSESQUIOXANES - SOLUBLE ORGANIC ANALOGS OF ALUMINOSILICATES [J].

FEHER, FJ ;

BUDZICHOWSKI, TA ;

WELLER, KJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (18) :7288-7289

[39] OLEFIN POLYMERIZATION BY VANADIUM-CONTAINING SILSESQUIOXANES - SYNTHESIS OF A DIALKYL OXO VANADIUM(V) COMPLEX THAT INITIATES ETHYLENE POLYMERIZATION [J].

FEHER, FJ ;

BLANSKI, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) :5886-5887

[40] POLYHEDRAL OLIGOMETALLASILASESQUIOXANES AS MODELS FOR SILICA-SUPPORTED CATALYSTS - CHROMIUM ATTACHED TO 2 VICINAL SILOXY GROUPS [J].

FEHER, FJ ;

BLANSKI, RL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (22) :1614-1616

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