ON THE OCCURRENCE OF 2-DIMENSIONAL PHASE-TRANSITIONS OF URIDINE AT THE AQUEOUS-SOLUTION GOLD SINGLE-CRYSTAL INTERFACE

被引：39

作者：

SCHARFE, M

HAMELIN, A

BUESSHERMAN, C

机构：

[1] Service de Chimie Analytique, Faculté des Sciences, Université Libre de Bruxelles, B-1050 Brussels, C.P. 255, 2, Bld. du Triomphe

来源：

ELECTROCHIMICA ACTA | 1995年 / 40卷 / 01期

关键词：

CONDENSED LAYERS; 2-DIMENSIONAL PHASE TRANSITIONS; CONDENSATION KINETICS; GOLD SINGLE CRYSTAL ELECTRODES; URIDINE;

D O I：

10.1016/0013-4686(94)00245-V

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The adsorption of uridine from 0.1M KClO4 on gold (111) and gold (210) electrodes has been examined with as main objective the detection of 2D condensed phases. The formation of an organized layer of uridine at Au(111) is supported by the occurrence of sharp spikes in the i-E and C-E curves, the influence of the surfactant concentration and the temperature on the extent of the phase, the presence of a marked hysteresis and the associated kinetics which are controlled by a nucleation and growth mechanism.

引用

页码：61 / 67

页数：7

共 45 条

[41] SELF-ASSEMBLY OF MOLECULAR SUPERSTRUCTURES STUDIED BY INSITU SCANNING TUNNELING MICROSCOPY - DNA BASES ON AU(111) [J].

TAO, NJ ;

DEROSE, JA ;

LINDSAY, SM .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (04) :910-919

[42] PHASE-TRANSITION PROCESSES DISPLAYED BY COUMARIN MONOLAYERS AT THE WATER MERCURY INTERPHASE [J].

THOMAS, FG ;

BUESSHERMAN, C ;

GIERST, L .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 214 (1-2) :597-613

[43]

THOMAS FG, 1983, J ELECTROANAL CHEM, V154, P293

[44] SOLVENT EFFECTS ON THE 2-DIMENSIONAL CONDENSATION OF 2-THIOURACIL [J].

WANDLOWSKI, T ;

CHAIYASITH, P ;

BAUMGARTL, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 346 (1-2) :271-279

[45] ON THE STABILITY OF RECONSTRUCTED GOLD SURFACES IN AN ELECTROCHEMICAL-CELL [J].

ZEI, MS ;

LEHMPFUHL, G ;

KOLB, DM .

SURFACE SCIENCE, 1989, 221 (1-2) :23-34

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