OCTAKIS(ALKYLTHIO)-SUBSTITUTED PHTHALOCYANINES AND THEIR INTERACTIONS WITH SILVER(I) AND PALLADIUM(II) IONS

被引：183

作者：

GUREK, AG

BEKAROGLU, O

机构：

[1] TUBITAK,DEPT CHEM,MARMARA RES CTR,POB 21,GEBZE 41470,TURKEY

[2] TECH UNIV ISTANBUL,DEPT CHEM,ISTANBUL,TURKEY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 09期

关键词：

D O I：

10.1039/dt9940001419

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-free phthalocyanines and metal phthalocyaninates (M = Ni, Cu, Co or Zn) carrying eight alkylthio-groups on peripheral positions have been synthesised from 4,5-bis(alkylthio)phthalonitrile and 1,8-diazabicyclo[5.4.0]undec-7-ene (dbu) or the corresponding anhydrous metal salt [NiCl2, CuCl, CoCl2 or Zn(O2CMe)2]. The resulting compounds reacted with silver(I) or palladium(II) salts to form complexes with a phthalocyanine:metal ratio of 1:4. Spectrophotochemical investigation of these reactions revealed that complexation with Ag(I) results in aggregation, while the addition of Pd(II) destroys the aggregation and yields a new Q band at 720 nm.

引用

页码：1419 / 1423

页数：5

共 34 条

[1] SYNTHESIS AND CHARACTERIZATION OF METAL-FREE AND METAL DERIVATIVES OF A NOVEL SOLUBLE CROWN-ETHER-CONTAINING PHTHALOCYANINE
AHSEN, V
YILMAZER, E
ERTAS, M
BEKAROGLU, O
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (02): : 401 - 406
[2] SYNTHESIS AND CHARACTERIZATION OF CROWN-ETHER-CONTAINING PHTHALOCYANINES WITH GROUP-IV-A ELEMENTS
AHSEN, V
YILMAZER, E
GUREK, A
GUL, A
BEKAROGLU, O
[J]. HELVETICA CHIMICA ACTA, 1988, 71 (07) : 1616 - 1621
[3] NOVEL PHTHALOCYANINES WITH AZA CROWN ETHER MOIETIES
AHSEN, V
GUREK, A
MUSLUOGLU, E
BEKAROGLU, O
[J]. CHEMISCHE BERICHTE, 1989, 122 (06) : 1073 - 1074
[4] DEPENDENCE OF COMPLEX STRUCTURE ON LIGAND CONFORMATION IN PALLADIUM(II) COMPLEXES OF THE CROWN THIOETHER LIGANDS 2,5,8-TRITHIA[9]-ORTHO-BENZENOPHANE (TT[9]OB) AND 2,5,8-TRITHIA[9]-META-BENZENOPHANE (TT[9]MB) - STRUCTURES OF PDCL2(TT[9]OB).DMSO AND PDCL2(TT[9]MB)
DEGROOT, B
HANAN, GS
LOEB, SJ
[J]. INORGANIC CHEMISTRY, 1991, 30 (24) : 4644 - 4647
[5] Duggan PJ, 1985, Eur. Pat. Appl., Patent No. [EP0155780 A2, 0155780]
[6] SELF-ASSEMBLING FEATURES OF SOLUBLE NICKEL PHTHALOCYANINES
FUJIKI, M
TABEI, H
KURIHARA, T
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (05) : 1281 - 1285
[7] SYNTHESIS, CHARACTERIZATION AND ELECTRICAL-PROPERTIES OF PHTHALOCYANINES SUBSTITUTED WITH 17-MEMBERED TRIOXADIAZA MACROCYCLES
GUMUS, G
OZTURK, ZZ
AHSEN, V
GUL, A
BEKAROGLU, O
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (16): : 2485 - 2489
[8] SYNTHESIS OF TETRAALKYLTHIO-SUBSTITUTED PHTHALOCYANINES AND THEIR COMPLEXATION WITH AG(I) AND PD(II)
GUROL, I
AHSEN, V
BEKAROGLU, O
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (04): : 497 - 500
[9] SYNTHESIS AND CHARACTERIZATION OF SOLUBLE PHTHALO-CYANINES - STRUCTURE-PROPERTY RELATIONSHIP
HANACK, M
GUL, A
HIRSCH, A
MANDAL, BK
SUBRAMANIAN, LR
WITKE, E
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1990, 187 : 365 - 382
[10] POLYTOPIC LIGAND SYSTEMS - SYNTHESIS AND COMPLEXATION PROPERTIES OF A CROWNED PHTHALOCYANINE
HENDRIKS, R
SIELCKEN, OE
DRENTH, W
NOLTE, RJM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (19) : 1464 - 1465

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