OCTAKIS(ALKYLTHIO)-SUBSTITUTED PHTHALOCYANINES AND THEIR INTERACTIONS WITH SILVER(I) AND PALLADIUM(II) IONS

被引：183

作者：

GUREK, AG

BEKAROGLU, O

机构：

[1] TUBITAK,DEPT CHEM,MARMARA RES CTR,POB 21,GEBZE 41470,TURKEY

[2] TECH UNIV ISTANBUL,DEPT CHEM,ISTANBUL,TURKEY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 09期

关键词：

D O I：

10.1039/dt9940001419

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-free phthalocyanines and metal phthalocyaninates (M = Ni, Cu, Co or Zn) carrying eight alkylthio-groups on peripheral positions have been synthesised from 4,5-bis(alkylthio)phthalonitrile and 1,8-diazabicyclo[5.4.0]undec-7-ene (dbu) or the corresponding anhydrous metal salt [NiCl2, CuCl, CoCl2 or Zn(O2CMe)2]. The resulting compounds reacted with silver(I) or palladium(II) salts to form complexes with a phthalocyanine:metal ratio of 1:4. Spectrophotochemical investigation of these reactions revealed that complexation with Ag(I) results in aggregation, while the addition of Pd(II) destroys the aggregation and yields a new Q band at 720 nm.

引用

页码：1419 / 1423

页数：5

共 34 条

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