POTASSIUM TETRACARBONYLHYDRIDOFERRATE - A REAGENT FOR THE SELECTIVE REDUCTION OF CARBONYL GROUPS

被引：6

作者：

BRUNET, JJ ^{[1
]}

CHAUVIN, R ^{[1
]}

KINDELA, F ^{[1
]}

NEIBECKER, D ^{[1
]}

机构：

[1] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 47期

关键词：

POTASSIUM TETRACARBONYLHYDRIDOFERRATE; KETONES; 1,2-DICARBONYL COMPOUNDS; SELECTIVE REDUCTION;

D O I：

10.1016/S0040-4039(00)78502-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

KHFe(CO)(4) is an efficient reagent for the reduction of electron-deficient ketones (trifluoroacetophenone) and for the selective mono-reduction of the keto group of alpha-ketocarbonyl compounds such as benzil, methyl benzoylformate, N-methylisatine and methyl pyruvate. The phosphite substituted derivative K[HFe(CO)(3){P(OMe)(3)}] is also an efficient reagent for the reduction of trifluoroacetophenone.

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页码：8801 / 8804

页数：4

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