A SUM-FREQUENCY STUDY OF THE 2-DIMENSIONAL PHASE-TRANSITION IN A MONOLAYER OF UNDECANOL ON WATER

被引：64

作者：

BRAUN, R ^{[1
]}

CASSON, BD ^{[1
]}

BAIN, CD ^{[1
]}

机构：

[1] UNIV OXFORD,PHYS & THEORET CHEM LAB,OXFORD OX1 3QZ,ENGLAND

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 245卷 / 4-5期

关键词：

D O I：

10.1016/0009-2614(95)01041-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sum-frequency (SF) vibrational spectra are presented of monolayers of 1-undecanol on water in the vicinity of the first-order phase transition at 28 degrees C. A combined analysis of SF and ellipsometric data permits the calculation of the molecular tilt and area per molecule in the high-temperature phase. The SF spectra demonstrate that the monolayer remains highly conformationally ordered above the phase transition.

引用

页码：326 / 334

页数：9

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