REGIO-CONTROLLED ENE-YNE PHOTOCHEMICAL [2+2] CYCLOADDITION USING SILICON AS A TETHER

被引：18

作者：

BRADFORD, CL ^{[1
]}

FLEMING, SA ^{[1
]}

WARD, SC ^{[1
]}

机构：

[1] BRIGHAM YOUNG UNIV,DEPT CHEM,PROVO,UT 84602

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 24期

基金：

美国国家科学基金会;

关键词：

2+2 PHOTOCYCLOADDITION; ALKOXYSILANE PHOTOCHEMISTRY; CYCLOBUTENE SYNTHESIS;

D O I：

10.1016/0040-4039(95)00793-C

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Substituted cyclobutenes were synthesized by irradiation of silicon tethered ene-ynes. Irradiation of a silicon tethered bisphenylalkyne resulted in cycloaddition and rearrangement to a substituted naphthalene. A diradical intermediate which resembles known DNA cleaving molecules is proposed.

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收藏

页码：4189 / 4192

页数：4

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