REACTIONS OF ALKYNES WITH HOMOALLYLIC HALIDES MEDIATED BY ZIRCONOCENE-ETHYLENE COMPLEX

被引：23

作者：

TAKAHASHI, T

KONDAKOV, DY

SUZUKI, N

机构：

[1] Coordination Chemistry Laboratories, Institute for Molecular Science, Okazaki, 444, Myodaiji

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 41期

关键词：

D O I：

10.1016/0040-4039(93)88107-T

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of alkynes with zirconocene-ethylene complex and homoallylic halides gave allylcyclopropane derivatives.

引用

页码：6571 / 6574

页数：4

共 15 条

[1] CP2ZR(C2H4)(PME3), THE 1ST STABLE ETHYLENE COMPLEX OF ZIRCONIUM [J].

ALT, HG ;

DENNER, CE ;

THEWALT, U ;

RAUSCH, MD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 356 (03) :C83-C85

[2] (1-ALKENE)(TRIMETHYLPHOSPHINE)ZIRCONOCENES - PREPARATION, CHARACTERIZATION, AND REACTIVITY [J].

BINGER, P ;

MULLER, P ;

BENN, R ;

RUFINSKA, A ;

GABOR, B ;

KRUGER, C ;

BETZ, P .

CHEMISCHE BERICHTE, 1989, 122 (06) :1035-1042

[3] SELECTIVE, ZIRCONIUM-MEDIATED CROSS-COUPLING OF ALKYNES - SYNTHESIS OF ISOMERICALLY PURE 1,3-DIENES AND 1,4-DIIODO 1,3-DIENES [J].

BUCHWALD, SL ;

NIELSEN, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (08) :2870-2874

[4] FORMATION OF ZIRCONOCENE ETA-2-IMINE COMPLEXES BY REARRANGEMENT OF CYCLIC IMINOACYL COMPLEXES [J].

DAVIS, JM ;

WHITBY, RJ ;

JAXACHAMIEC, A .

TETRAHEDRON LETTERS, 1992, 33 (38) :5655-5658

[5]

LONGONE DT, 1967, J CHEM SOC CHEM COMM, P447

[6] NOVEL HEAD-TO-TAIL ALKYL-ALKENE OR ALKENE-ALKENE COUPLING VIA ZIRCONIUM-CATALYZED REACTION OF ALKYLMAGNESIUM DERIVATIVES WITH MONOSUBSTITUTED ALKENES [J].

ROUSSET, CJ ;

NEGISHI, EI ;

SUZUKI, N ;

TAKAHASHI, T .

TETRAHEDRON LETTERS, 1992, 33 (15) :1965-1968

[7]

SUZUKI N, UNPUB J AM CHEM SOC

[8] FACILE CLEAVAGE OF THE C-BETA-C-BETA'-BOND OF ZIRCONACYCLOPENTENES - CONVENIENT METHOD FOR SELECTIVELY COUPLING ALKYNES WITH ALKYNES, NITRILES, AND ALDEHYDES [J].

TAKAHASHI, T ;

KAGEYAMA, M ;

DENISOV, V ;

HARA, R ;

NEGISHI, E .

TETRAHEDRON LETTERS, 1993, 34 (04) :687-690

[9] ZIRCONOCENE-ALKENE COMPLEXES - AN X-RAY STRUCTURE AND A NOVEL PREPARATIVE METHOD [J].

TAKAHASHI, T ;

MURAKAMI, M ;

KUNISHIGE, M ;

SABURI, M ;

UCHIDA, Y ;

KOZAWA, K ;

UCHIDA, T ;

SWANSON, DR ;

NEGISHI, E .

CHEMISTRY LETTERS, 1989, (05) :761-764

[10] REACTION OF DIMETHYLZIRCONOCENE WITH ALKYLMAGNESIUM HALIDES AS A POTENTIALLY GENERAL-METHOD FOR PREPARING ZIRCONOCENE-ALKENE COMPLEXES [J].

TAKAHASHI, T ;

NITTO, Y ;

SEKI, T ;

SABURI, M ;

NEGISHI, E .

CHEMISTRY LETTERS, 1990, (12) :2259-2262

← 1 2 →