RADICAL-INDUCED FRAGMENTATIONS OF KETOEPOXIDES

被引：12

作者：

BREEN, AP ^{[1
]}

MURPHY, JA ^{[1
]}

PATTERSON, CW ^{[1
]}

WOOSTER, NF ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,UNIV PK,NOTTINGHAM NG7 2RD,ENGLAND

来源：

TETRAHEDRON | 1993年 / 49卷 / 46期

关键词：

D O I：

10.1016/S0040-4020(01)81554-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cleavage of alpha-ketoepoxycarbinyl radicals has been investigated for six substrates using two methods of radical formation. Products resulting from carbon-oxygen bond cleavage were observed in each case, but vinyl ethers derived from epoxide carbon-carbon cleavage were isolated in one case.

引用

页码：10643 / 10654

页数：12

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