SURFACE INTERACTION BETWEEN METHANE AND ALKALI ALKALINE-EARTH OXIDE CATALYSTS

被引：18

作者：

GRZYBEK, T

BAERNS, M

机构：

[1] Ruhr-University Bochum, D-4630 Bochum

来源：

JOURNAL OF CATALYSIS | 1991年 / 129卷 / 01期

关键词：

D O I：

10.1016/0021-9517(91)90014-U

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The interaction of methane with alkali/alkaline-earth oxide catalysts (NaOHCaO, NaOHBaOCaO) was investigated at 350, 500 and 750°C using X-ray photoelectron spectroscopy. Methane interacted with surface carbonate at temperatures of 500 and 750°C while no reaction was observed at 350°C. Intermediate states registered on the surface consisted of methoxy species and carbonyl groups. Mechanistic aspects of the high-temperature oxidative methane conversion reaction tentatively derived from these results are discussed. © 1991.

引用

页码：106 / 113

页数：8