CATALYTIC ASYMMETRIC INDUCTION OF PLANAR CHIRALITY - PALLADIUM-CATALYZED ASYMMETRIC CROSS-COUPLING OF MESO TRICARBONYL(ARENE)CHROMIUM COMPLEXES WITH ALKENYLBORONIC AND ARYLBORONIC ACIDS

被引：57

作者：

UEMURA, M

NISHIMURA, H

HAYASHI, T

机构：

[1] HOKKAIDO UNIV,CATALYSIS RES CTR,SAPPORO,HOKKAIDO 060,JAPAN

[2] HOKKAIDO UNIV,GRAD SCH PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 473卷 / 1-2期

关键词：

(ARENE)CHROMIUM; PLANAR CHIRALITY; CATALYTIC ASYMMETRIC CROSS-COUPLING; CHIRAL LIGAND;

D O I：

10.1016/0022-328X(94)80113-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Asymmetric cross-coupling of tricarbonyl(o-dichlorobenzene)chromium with alkenyl- and arytmetals in the presence of a chiral phosphine-palladium catalyst gave the mono-coupling products at up to 69% ee.

引用

页码：129 / 137

页数：9

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