CHEMOSELECTIVE CARBON-CARBON BOND FORMATION REACTIONS OF ZIRCONACYCLOPENTENES

被引：59

作者：

KASAI, K

KOTORA, M

SUZUKI, N

TAKAHASHI, T

机构：

[1] INST MOLEC SCI,COORDINAT CHEM LABS,OKAZAKI,AICHI 444,JAPAN

[2] GRAD UNIV ADV STUDIES,OKAZAKI,AICHI 444,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 01期

关键词：

D O I：

10.1039/c39950000109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of zirconacyclopentenes with allyl chloride in the presence of a copper salt and a lithium or magnesium salt proceeds at the alkenyl carbon on zirconium with high chemoselectivity; selective C-C bond formation at the alkyl carbon was also achieved by treatment of zirconacyclopentenes with a copper salt and a lithium or magnesium salt, methanol and allyl chloride.

引用

页码：109 / 110

页数：2

共 17 条

[11] PAIR-SELECTIVE COUPLING OF ALKYNES WITH ALKENES ON ZIRCONOCENE COMPLEX
TAKAHASHI, T
XI, ZF
ROUSSET, CJ
SUZUKI, N
[J]. CHEMISTRY LETTERS, 1993, (06) : 1001 - 1004
[12] FACILE CLEAVAGE OF THE C-BETA-C-BETA'-BOND OF ZIRCONACYCLOPENTENES - CONVENIENT METHOD FOR SELECTIVELY COUPLING ALKYNES WITH ALKYNES, NITRILES, AND ALDEHYDES
TAKAHASHI, T
KAGEYAMA, M
DENISOV, V
HARA, R
NEGISHI, E
[J]. TETRAHEDRON LETTERS, 1993, 34 (04) : 687 - 690
[13] HIGHLY CHEMOSELECTIVE REACTIONS OF ZIRCONACYCLOPENTENES FOR SELECTIVE FUNCTIONALIZATION
TAKAHASHI, T
AOYAGI, K
HARA, R
SUZUKI, N
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (13) : 1042 - 1044
[14] A REAGENT-DEPENDENT HIGHLY CHEMOSELECTIVE HALOGENATION REACTION OF ZIRCONACYCLOPENTENES
TAKAHASHI, T
AOYAGI, K
KONDAKOV, DY
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (06) : 747 - 748
[15] COPPER-CATALYZED C-C BOND FORMATION REACTION OF ALLYLZIRCONATION PRODUCTS OF ALKYNES
TAKAHASHI, T
KOTORA, M
KASAI, K
SUZUKI, N
[J]. TETRAHEDRON LETTERS, 1994, 35 (31) : 5685 - 5688
[16] NOVEL SYNTHESES OF 8-MEMBERED-5-MEMBERED FUSED-RING COMPOUNDS FROM ZIRCONACYCLOPENTADIENES
TAKAHASHI, T
KOTORA, M
KASAI, K
SUZUKI, N
NAKAJIMA, K
[J]. ORGANOMETALLICS, 1994, 13 (11) : 4183 - 4185
[17] COPPER-CATALYZED ALLYLIC ALKYLATIONS OF ALKYLZIRCONIUM INTERMEDIATES
VENANZI, LM
LEHMANN, R
KEIL, R
LIPSHUTZ, BH
[J]. TETRAHEDRON LETTERS, 1992, 33 (40) : 5857 - 5860

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