SCANNING TUNNELING MICROSCOPY AND TUNNELING SPECTROSCOPY OF N-TYPE IRON PYRITE (N-FES2) SINGLE-CRYSTALS

被引:37
作者
FAN, FR [1 ]
BARD, AJ [1 ]
机构
[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712
关键词
D O I
10.1021/j100158a016
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The (001) surface of a highly doped (> 2.7 x 10(18) cm-3) n-type FeS2 crystal was imaged by the constant current mode in air with a scanning tunneling microscope (STM). Current (i) images at different bias voltages (V) were also obtained. Tunneling spectroscopy (TS) was carried out, and i vs V and di/dV vs V curves obtained with the tip held above the FeS2 surface were interpreted in terms of the band locations and a localized state within the band gap. The effect of band bending in the semiconductor on the interpretation of the TS results is also considered.
引用
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页码:1969 / 1976
页数:8
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