A LOW-ENERGY-ELECTRON DIFFRACTION ANALYSIS OF THE (ROOT-3X-ROOT-3) R30-DEGREES STRUCTURE OF MOLECULAR NITROGEN ADSORBED ON RU(0001)

被引:29
作者
BLUDAU, H
GIERER, M
OVER, H
ERTL, G
机构
[1] Fritz-Haber-Institute der Max-Planck-Gesellschaft, D-14195 Berlin Dahlem
关键词
D O I
10.1016/0009-2614(94)00101-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structural parameters of the (square-root 3 x square-root 3)R30-degrees overlayer formed by N2 adsorption on Ru(0001) have been determined by a LEED IV analysis. The N2 molecules are coordinated to the surface at on-top sites with the interatomic axis perpendicular to the surface. The N-N bond length turns out to be 1.10 +/- 0.04 angstrom which equals the bond length of gaseous N2. The interaction of N2 with Ru (0001) is characterized by a lack of pronounced substrate distortions.
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页码:452 / 456
页数:5
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