ENANTIOSELECTIVE SYNTHESIS OF HYDROXYETHYLOXIRANECARBOXYLIC ACID-DERIVATIVES BY EPOXIDATION OF 5-YLIDENE-1,3-DIOXANE-4-ONES

被引：8

作者：

BARTELTS, A

JONES, PG

LIEBSCHER, J

机构：

[1] HUMBOLDT UNIV BERLIN,INST CHEM,D-10115 BERLIN,GERMANY

[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 07期

关键词：

D O I：

10.1016/0957-4166(95)00193-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Epoxidation of the 5-ylidene-1,3-dioxane-4-ones 3 with dimethyldioxirane (4) affords enantiomerically pure oxiranes 5 in satisfactory yields. These products 5 are novel hydroxyethyloxiranecarboxylic acid derivatives and can be reduced to enantiomerically pure 5-(alpha-hydroxyalkyl)- 1,3-dioxane-4-ones 6.

引用

页码：1539 / 1542

页数：4

共 10 条

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