SYNTHESIS AND RING-OPENING POLYMERIZATION OF HIGHLY STRAINED, RING-TILTED [2]RUTHENOCENOPHANES

被引：79

作者：

NELSON, JM

LOUGH, AJ

MANNERS, I

机构：

[1] Department of Chemistry, University of Toronto, Toronto, Ontario, M5S 1A1

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 09期

关键词：

D O I：

10.1002/anie.199409891

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Only an ethylene bridge braces the Cp2Ru unit in the first [2]rutheno‐cenophane. This leads to a highly strained molecular framework (shown on the right) and makes [2]ruthenocenophanes suitable starting materials for thermal ring‐opening polymerization to give poly‐(ruthenocenylethylene)s. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：989 / 991

页数：3

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