STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .39. EXAMINATION OF THE ABILITY OF THE C-13 NMR SHIFT-SIGMA-C+ CORRELATION FOR SUBSTITUTED BENZYLIC CATIONS TO ACCOMMODATE THE HIGHLY ELECTRON DONATING 5-COUMARANYL MOIETY - EVALUATION OF THE SIGNIFICANCE OF THE RHO-C+ VALUES OBSERVED FOR THE SIMPLE ARYLDIALKYL CARBOCATIONS

被引：12

作者：

BROWN, HC

PERIASAMY, M

机构：

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1982年 / 47卷 / 01期

关键词：

D O I：

10.1021/jo00340a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：5 / 8

页数：4

共 13 条

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[3] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .22. EFFECT OF RING SIZE ON STABILIZATION OF DEVELOPING CARBOCATIONS AS REVEALED BY TOOL OF INCREASING ELECTRON DEMAND [J].

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[4] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .23. NEW SIGMA-+ CONSTANTS FOR ACTIVATING SUBSTITUENTS - SOLVOLYSIS OF 1-ARYL-1-CYCLOPROPYL 3,5-DINITROBENZOATES CONTAINING ACTIVATING SUBSTITUENTS IN ARYL GROUP - TOOL OF INCREASING ELECTRON DEMAND AND I-STRAIN [J].

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[5] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .34. C-13 NMR-STUDIES OF CARBOCATIONS .4. EFFECT OF INCREASING ELECTRON DEMAND ON THE C-13 NMR SHIFTS IN SUBSTITUTED TERT-CUMYL AND 1-ARYL-1-CYCLOPENTYL CARBOCATIONS - CORRELATION OF THE DATA BY A NEW SET OF SUBSTITUENT CONSTANTS, SIGMA-C+ [J].

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[6] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .37. EFFECT OF INCREASING ELECTRON DEMAND ON C-13 NUCLEAR MAGNETIC-RESONANCE SHIFTS IN THE 9-ARYL-EXO-5,6-TRIMETHYLENE AND 9-ARYL-ENDO-5,6-TRIMETHYLENE-9-NORBORNYL CARBOCATIONS - EFFECT OF THE CATIONIC CARBON CENTER ON REMOTE CARBON-ATOMS IN THE SKELETON AS REVEALED BY INCREASING ELECTRON DEMANDAR [J].

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JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (16) :3166-3170

[7] EFFECT OF COPLANARITY ON RATES OF SOLVOLYSIS OF SEVERAL T-CUMYL CHLORIDE DERIVATIVES - ELECTROPHILIC SUBSTITUENT CONSTANTS FOR POLYCYCLIC AROMATICS [J].

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[8]

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[10] C-13 NUCLEAR MAGNETIC-RESONANCE STUDIES OF CARBOCATIONS .5. EFFECT OF INCREASING ELECTRON DEMAND ON THE C-13 CHEMICAL-SHIFTS OF 3-ARYL-3-PENTYL AND 2-ARYL-2-ADAMANTYL CARBOCATIONS - CORRELATION OF DELTA-DELTA-C+ WITH ENHANCED SUBSTITUENT CONSTANTS SIGMA-C+ [J].

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JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (08) :1650-1653

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