SYNTHESIS AND CRYSTAL-STRUCTURE OF [K(C12H24O6)][U(ETA-C7H7)(2)], THE FIRST CYCLOHEPTATRIENYL SANDWICH COMPOUND

被引：48

作者：

ARLIGUIE, T ^{[1
]}

LANCE, M ^{[1
]}

NIERLICH, M ^{[1
]}

VIGNER, J ^{[1
]}

EPHRITIKHINE, M ^{[1
]}

机构：

[1] CEA SACLAY,CRISTALLOG LAB,CNRS,URA 331,SERV CHIM MOLEC,F-91191 GIF SUR YVETTE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 02期

关键词：

D O I：

10.1039/c39950000183

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound was prepared by treating a mixture of UCl4 and K with C7H8 or by reacting UCl4 with KC7H9; the crystal structure shows that the two C7H7 ligands are planar, parallel and perpendicular to the linear axis defined by the uranium atom and the ring centroids.

引用

页码：183 / 184

页数：2

共 16 条

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