THERMALLY REVERSIBLE CROSS-LINKING OF POLYSTYRENE VIA THE FURAN-MALEIMIDE DIELS-ALDER REACTION

被引：103

作者：

CANARY, SA

STEVENS, MP

机构：

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1992年 / 30卷 / 08期

关键词：

DIELS-ALDER CROSS-LINKING; POLYSTYRENE; THERMALLY REVERSIBLE CROSS-LINKING;

D O I：

10.1002/pola.1992.080300829

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Mixtures of maleimidomethylated polystyrene with difurfuryl adipate or with furfuryl alcohol-esterified poly [styrene-co-(maleic anhydride)] underwent thermally reversible Diels-Alder crosslinking. Reversal of crosslinking occurred rapidly at 150-degrees-C. The instability of the furfuryl group, however, limits the practicability of the reaction.

引用

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页码：1755 / 1760

页数：6

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