DIFFERENT MAGNETIC-PROPERTIES OF CHARGE-TRANSFER COMPLEXES AND CATION-RADICAL SALTS OF TETRATHIAFULVALENE DERIVATIVES SUBSTITUTED WITH IMINO PYROLIDINE-1-OXYLS AND PIPERIDINE-1-OXYLS

被引：29

作者：

SUGIMOTO, T ^{[1
]}

YAMAGA, S ^{[1
]}

NAKAI, M ^{[1
]}

TSUJII, M ^{[1
]}

NAKATSUJI, H ^{[1
]}

HOSOITO, N ^{[1
]}

机构：

[1] KYOTO UNIV, INST CHEM RES, UJI, KYOTO 611, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 11期

关键词：

D O I：

10.1246/cl.1993.1817

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The magnetic properties of charge-transfer (CT) complexes and cation radical salts of tetrathiafulvalene (TTF) derivatives bearing two different radical substituents were investigated. Preferential spin interactions occurred between TTF cation radical (TTF+.) and an acceptor anion radical for the CT complexes, and between two TTF+.'s for the cation radical salts, respectively. In addition, the magnitude was markedly different by the kind of radical substituent, which behaved as an isolated spin.

引用

页码：1817 / 1820

页数：4

共 7 条

[1] ANOMALOUS PARAMAGNETISM OF COPPER ACETATE [J].