A CONVENIENT SYNTHESIS OF O-ETHYL-1-AMINOALKYLPHOSPHINATES

被引：18

作者：

GAJDA, T

机构：

[1] Institute of Organic Chemistry, Technical University (Politechnika), 90-924 Lodz

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1993年 / 85卷 / 1-4期

关键词：

1-AMINOALKYLPHOSPHINATES; 1-HYDROXYALKYLPHOSPHINATES; MITSUNOBU REACTION; STAUDINGER REACTION; AZIDATION;

D O I：

10.1080/10426509308038182

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1-Aminoalkylphosphinates 4 have been obtained in good yields in a one-step transformation by the Mitsunobu reaction of 1-hydroxyalkylphosphinates 1 with hydrazoic acid, and subsequent treatment of the intermediate azides 2, with triphenylphosphine, followed by hydrolysis of the iminophosphoranes 3 with water.

引用

页码：59 / 64

页数：6

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