(3)INFINITY[(COCP(2)) SUBSET-OF FE(MU-CNSNME(3)NC)(3)] - A PURELY ORGANOMETALLIC CHANNEL INCLUSION COMPOUND

被引：50

作者：

SCHWARZ, P

SIEBEL, E

FISCHER, RD

APPERLEY, DC

DAVIES, NA

HARRIS, RK

机构：

[1] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,D-20146 HAMBURG,GERMANY

[2] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 11期

关键词：

COBALT COMPOUNDS; HOST-GUEST CHEMISTRY; INCLUSION COMPOUNDS; IRON COMPOUNDS; ZEOLITES;

D O I：

10.1002/anie.199511971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Only every second channel of the novel host–guest compound 1 is occupied by stacks of cobaltocenium ions (see picture on the right). The channel inclusion compound is formed by spontaneous self‐assembly of [CoCp2]+, Me3Sn+, and [Fe(CN)6]4− ions in H2O. The combination of X‐ray crystallography and multinucleus CP/MAS NMR spectroscopy gave optimal insights into the static and dynamic behavior. (Figure Presented.) (Formula Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1197 / 1199

页数：3

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