NOVEL SECONDARY ALLENYLIDENE RUTHENIUM COMPLEXES AND PREPARATION OF TRANS-[(DPPM)(2)(H)RU-C-EQUIVALENT-TO-C-CH(OME)R] DERIVATIVES

被引：39

作者：

PIRIO, N ^{[1
]}

TOUCHARD, D ^{[1
]}

DIXNEUF, PH ^{[1
]}

机构：

[1] UNIV RENNES 1,CHIM COORDINAT ORGAN LAB,CNRS,URA 415,F-35042 RENNES,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 462卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83386-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

cis-[(dppm)(2)Cl2Ru], 1 (dppm=Ph(2)PCH(2)PPh(2)) reacts with H-C=C-CH(OH)R and NaPF6 to give secondary allenylidene complexes trans-[(dppm)(2)ClRu=C=C=CHR][PF6], 3 [R = Ph (a), p-Ph-Cl (b), p-PhOMe (c), or trans-CH=CHPh (d)]. Complex 3a treated with NaBH4 gives trans-[(dppm)(2)ClRu-C=C-CH(2)Ph], 6a and the reaction of 3a-c with MeONa in MeOH affords trans-[(dppm)(2)(H)Ru-C=C-CH(OMe)R], 7a-c.

引用

页码：C18 / C20

页数：3

共 10 条

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