TUNNELING SPLITTINGS IN MODEL 2D POTENTIALS .1. V(X, Y) = V(0)(Y(2)-Y(0)2)(2)+1/2-OMEGA(1)2X(2)+1/4-ALPHA-X(4)+CX(2)Y(2)

被引:18
作者
BENDERSKII, VA [1 ]
GREBENSHCHIKOV, SY [1 ]
MILNIKOV, GV [1 ]
VETOSHKIN, EV [1 ]
机构
[1] RUSSIAN ACAD SCI, INST STRUCT MACROKINET, CHERNOGOLOVKA 142432, RUSSIA
关键词
D O I
10.1016/0301-0104(94)00147-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We propose a semiclassical method for calculating tunneling splittings, DELTA(n1n2), of the vibrationally excited states in 2D 'squeezed' potential. Semiclassical wavefunctions in the classically forbidden region are found in the vicinity of the extreme real trajectory in the inverted potential, and 2D version of the Liftshitz' formula, which relates splitting to the probability flux through the dividing plane, is employed to calculate DELTA(n1n2). Computations have been performed for different values of coupling strength and anharmonicity parameter. The results are compared with exact splittings and wavefunctions obtained by diagonalization of the 2D Hamiltonian. It is shown, that for small positive and arbitrary negative couplings the WKB method is accurate enough to reproduce correctly the change of tunneling splitting in progressions. WKB wavefunctions are in reasonable agreement with the exact ones in this case. Disagreement shows up with increasing C > 0 for high vibrational levels, when extreme trajectories of other types can come into play.
引用
收藏
页码:19 / 31
页数:13
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