REACTION OF DISUBSTITUTED 1,3-BUTADIYNES R1C-EQUIVALENT-TO-CC-EQUIVALENT-TO-CR-2 WITH ZIRCONOCENE COMPLEXES - CLEAVAGE OF THE CENTRAL C-C SINGLE BOND TO FORM SYMMETRICALLY AND UNSYMMETRICALLY DOUBLY ACETYLIDE-BRIDGED METALLOCENE COMPLEXES

被引：68

作者：

ROSENTHAL, U

OHFF, A

BAUMANN, W

KEMPE, R

TILLACK, A

BURLAKOV, VV

机构：

[1] Max-Planck-Gesellschaft, Arbeitsgruppe “Komplexkatalyse” an, Universität Rostock, 18055 Rostock

[2] Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 07期

关键词：

D O I：

10.1021/om00019a056

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

It has been shown that the zirconocene complex Cp2Zr(THF) (Me3SiC2SiMe3) readily reacts with disubstituted butadiynes R1C=CC=CR2 (R1 = R2 = SiMe3; R1 = SiMe3, R2 = (t)Bu or Ph) to form the dimeric symmetrical complex [Cp2Zr(mu-eta1:eta2-C=CSiMe3)]2 (2) and doubly acetylide-bridged, unsymmetrical complexes [Cp2Zr(mu-eta1:eta2-C=CSiMe3) (mu-eta1:eta2-C=C(t)Bu)ZrCp2] (3) and [Cp2Zr(mu-eta1:eta2-C=CSiMe3) (mu-eta1:eta2-C=CPh)ZrCp2] (4), respectively. The structure of the products has been established by X-ray structure analyses.

引用

页码：2903 / 2906

页数：4

共 17 条

[11] FORMATION OF [CP2TI(CCSIME3)] FROM TITANOCENE AND 1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE [J].