FORMATION OF FULLERENES AND ENDOHEDRAL METALLOFULLERENES - PREPARATION IN A RADIOFREQUENCY FURNACE

被引：35

作者：

JANSEN, M

PETERS, G

WAGNER, N

机构：

[1] Institut für Anorganische Chemie, Bonn, D-53121

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 04期

关键词：

FULLERENES; ENDOHEDRAL METALLOFULLERENES; PREPARATION; THERMODYNAMICS OF FORMATION;

D O I：

10.1002/zaac.19956210432

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A thermodynamic analysis of the reaction of formation is presented for C-60. The alternative route for the preparation of fullerenes by evaporating carbon in a RF-furnace is described. This process is characterized by its broad variability and by comparatively mild conditions which, in addition, may be measured and controlled rather precisely. Thus, it offers favourite facilities for the production of soots with high contents of fullerenes and endohedral fullerenes. So far, LaC82 could be extracted using toluene.

引用

页码：689 / 693

页数：5

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