ISOLATION OF A REMARKABLY STABLE HYDROGEN-BONDED DIMERIC MANGANESE(II) COMPLEX, [MN(L)(OH2)](2)(ME(2)SO)(2) FROM THE REDUCTION OF A MANGANESE(III) SCHIFF-BASE COMPLEX [L=THE DIANION OF N,N'-BIS(3-BROMO-5-NITROSALICYLIDENE)-1,2-DIAMINO-(2-METHYL)ETHANE]

被引：19

作者：

BERMEJO, MR ^{[1
]}

GARCIADEIBE, A ^{[1
]}

SANMARTIN, J ^{[1
]}

SOUSA, A ^{[1
]}

AURANGZEB, N ^{[1
]}

HULME, CE ^{[1
]}

MCAULIFFE, CA ^{[1
]}

PRITCHARD, RG ^{[1
]}

WATKINSON, M ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 05期

关键词：

D O I：

10.1039/c39940000645

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of [Mn(L)(OH2)](2)(Me(2)SO)(2) [L = the dianion of N,N'-bis(3-bromo-5-nitrosalicylidene)-1,2-diamino-(2-methyl)ethane] shows it to be a strongly hydrogen-bonded dimer of manganese(II), produced by recrystallisation of a manganese(III) Schiff base acetate complex from dimethyl sulfoxide.

引用

页码：645 / 646

页数：2

共 29 条

[1] THE PHOTOLYSIS OF COORDINATED WATER IN [MN(SALTM)(H2O)]2(CIO4)2 [SALTM = N,N'-PROPYLENEBIS(SALICYLIDENEAMINATO)] [J].

ASHMAWY, FM ;

MCAULIFFE, CA ;

PARISH, RV ;

TAMES, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (01) :14-16

[2]

ASHWAMY FM, 1985, J CHEM SOC DA, P1391

[3] THE CRYSTAL-STRUCTURE OF [MN(SALPN)(ACETATE)]2(H2O)3 - THE 1ST EXAMPLE OF A MANGANESE(III) SCHIFF-BASE POLYMERIC COMPLEX CONTAINING A DIMERIC REPEAT UNIT [SALPN = N,N'-BIS(SALICYLIDENE)-1,3-DIAMINOPROPANE] [J].

AURANGZEB, N ;

HULME, CE ;

MCAULIFFE, CA ;

PRITCHARD, RG ;

WATKINSON, M ;

GARCIADEIBE, A ;

BERMEJO, MR ;

SOUSA, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (20) :1524-1526

[4] FACILE SYNTHESIS AND STRUCTURE OF THE MN-IV-MN-IV DINUCLEAR COMPLEX [MN(SALPN)O](2)(DMSO)(2)[SALPNH(2)=N,N'-BIS(SALICYLIDENE)-1,3-DIAMINOPROPANE] [J].

AURANGZEB, N ;

MCAULIFFE, CA ;

PRITCHARD, RG ;

WATKINSON, M ;

BERMEJO, M ;

GARCIADEIBE, A ;

SOUSA, A .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 (11) :1945-1947

[5]

AURANGZEB N, UNPUB

[6]

Beyer W.F., 1986, MANGANESE METABOLISM, P193

[7] FORMATION OF A (4+4) SCHIFF-BASE MACROCYCLIC LIGAND BY A TEMPLATE REARRANGEMENT - CRYSTAL AND MOLECULAR-STRUCTURES OF 2 TETRANUCLEAR MANGANESE(II) COMPLEXES [J].

BROOKER, S ;

MCKEE, V ;

SHEPARD, WB ;

PANNELL, LK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (11) :2555-2562

[8]

CHINIAE GM, 1970, BIOCHIM BIOPHYS ACTA, V197, P219

[9] MANGANESE CARBOXYLATE CHEMISTRY AND ITS BIOLOGICAL RELEVANCE [J].

CHRISTOU, G .

ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (09) :328-335

[10]

DISMUKES GC, 1986, MANGANESE METABOLISM, P275

← 1 2 3 →