EQUILIBRATION IN REVERSIBLE BIMOLECULAR REACTIONS

被引：51

作者：

EDELSTEIN, AL ^{[1
]}

AGMON, N ^{[1
]}

机构：

[1] HEBREW UNIV JERUSALEM, FRITZ HABER RES CTR, IL-91904 JERUSALEM, ISRAEL

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 15期

关键词：

D O I：

10.1021/j100015a024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fast reversible pseudo-unimolecular reactions do not approach equilibrium in the simple exponential fashion predicted by chemical rate equations. Many body effects in bimolecular reactions have been revealed in an extensive series of Brownian simulations, showing up to three distinct phases in the approach to equilibrium. Recent theoretical developments are compared with the simulation as well as with experimental data concerning the pH effect in excited-state proton transfer to solvent.

引用

页码：5389 / 5401

页数：13

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