BA[SI(OCH2CH2O)3], A HEXAALKOXYSILICATE SYNTHESIZED FROM SIO2

被引：45

作者：

HOPPE, ML

LAINE, RM

KAMPF, J

GORDON, MS

BURGGRAF, LW

机构：

[1] UNIV MICHIGAN,DEPT MAT SCI & ENGN,HH DOW BLDG,2300 HAYWARD ST,ANN ARBOR,MI 48109

[2] UNIV MICHIGAN,DEPT CHEM,ANN ARBOR,MI 48109

[3] N DAKOTA STATE UNIV,FARGO,ND 58105

[4] USAF,OFF SCI RES,WASHINGTON,DC 20330

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 02期

关键词：

D O I：

10.1002/anie.199302871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of BaO, SiO2, and an excess of ethylene glycol provides [Ba-Si(OCH2CH2O)3] . 3.25 HO(CH2)2OH, the first amazingly stable hexaalkylsilicate, in 90% yield. This complex was characterized by X-ray crystallography. The reactions with MgO and CaO give analogous compounds; with alkali metal oxides pentacoordinate silicates are formed.

引用

页码：287 / 289

页数：3

共 44 条

[1] REACTION OF CATECHOL WITH COLLOIDAL SILICA AND SILICIC ACID IN AQUEOUS AMMONIA
BARNUM, DW
[J]. INORGANIC CHEMISTRY, 1972, 11 (06) : 1424 - &
[2] CATECHOL COMPLEXES WITH SILICON
BARNUM, DW
[J]. INORGANIC CHEMISTRY, 1970, 9 (08) : 1942 - &
[3] REACTIVITY OF DIANIONIC HEXACOORDINATED SILICON COMPLEXES TOWARD NUCLEOPHILES - A NEW ROUTE TO ORGANOSILANES FROM SILICA
BOUDIN, A
CERVEAU, G
CHUIT, C
CORRIU, RJP
REYE, C
[J]. ORGANOMETALLICS, 1988, 7 (05) : 1165 - 1171
[4] REACTIVITY OF ANIONIC PENTACOORDINATED SILICON COMPLEXES TOWARDS NUCLEOPHILES
BOUDIN, A
CERVEAU, G
CHUIT, C
CORRIU, RJP
REYE, C
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (05): : 473 - 474
[5] UNEXPECTED REACTIVITY OF BIFUNCTIONAL HEXACOORDINATED SILICON SPECIES
BRELIERE, C
CORRIU, RJP
ROYO, G
MAN, WWCWC
ZWECKER, J
[J]. ORGANOMETALLICS, 1990, 9 (10) : 2633 - 2635
[6] Brinker C. J., 1990, SOL GEL SCI, DOI [10.1016/B978-0-08-057103-4.50013-1, DOI 10.1016/B978-0-08-057103-4.50013-1]
[7] BURGGRAF LW, 1986, MATER RES SOC S P, V73, P529
[8] LOW-TEMPERATURE SYNTHESES OF OLIVINE AND FORSTERITE FACILITATED BY HYDROGEN-PEROXIDE
BURLITCH, JM
BEEMAN, ML
RILEY, B
KOHLSTEDT, DL
[J]. CHEMISTRY OF MATERIALS, 1991, 3 (04) : 692 - 698
[9] REACTIVITY OF DIANIONIC HEXACOORDINATE GERMANIUM COMPLEXES TOWARD ORGANOMETALLIC REAGENTS - A NEW ROUTE TO ORGANOGERMANES
CERVEAU, G
CHUIT, C
CORRIU, RJP
REYE, C
[J]. ORGANOMETALLICS, 1991, 10 (05) : 1510 - 1515
[10] PENTACOORDINATE SILICON-COMPOUNDS - REACTIONS OF SILATRANES WITH NUCLEOPHILES
CERVEAU, G
CHUIT, C
CORRIU, RJP
NAYYAR, NK
REYE, C
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 389 (02) : 159 - 168

← 1 2 3 4 5 →