CONFORMATIONALLY RIGID DIAMIDE COMPLEXES - SYNTHESIS AND STRUCTURE OF TANTALUM(III) ALKYNE DERIVATIVES

被引：55

作者：

GUERIN, F ^{[1
]}

MCCONVILLE, DH ^{[1
]}

VITTAL, JJ ^{[1
]}

机构：

[1] UNIV WESTERN ONTARIO,DEPT CHEM,LONDON,ON N6A 5B7,CANADA

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 07期

关键词：

D O I：

10.1021/om00007a013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chelating diamide complexes mer-TaCl3(BDPP) (2), mer-TaCl3(BDPP) (3), and (BDPP)Ta(eta(2)-RC=CR)Cl (4a, R = Pr; 4b, R = Et; 4c, R = Ph) (BDPP = 2,6-(ArNCH2)(2)-NC5H3; Ar = 2,6-Pr-i(2)-C6H3), have been prepared. Proton and carbon NMR data suggest that the alkynes in 4a-c rotate rapidly on the NMR time scale. An X-ray study of(BDPP)Ta(eta(2)-PrC=CPr)Cl (4a) revealed a distorted-square-pyramidal geometry with the chloride occupying the apical position.

引用

页码：3154 / 3156

页数：3

共 21 条

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