CHIRALITY MEMORY CONTROLLED BY THE CRYSTAL-LATTICE OF A MOLECULAR-COMPOUND

被引：19

作者：

KOSHIMA, H ^{[1
]}

DING, KL ^{[1
]}

CHISAKA, Y ^{[1
]}

MATSUURA, T ^{[1
]}

机构：

[1] RYUKOKU UNIV,DEPT CHEM MAT,SETA KU,OTSU,SHIGA 520,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 01期

关键词：

D O I：

10.1016/0957-4166(94)00362-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Irradiation of crystalline charge transfer complex 3 formed between (S)-(+)-2-(6-methoxy-2-naphthyl)propanoic acid 1 and 1,2,4,5-tetracyanobenzene 2 is shown to lead to the optically active decarboxylated-coupled product (+)-4 in high yield and substantial enantiomeric excess. In this process the configuration of the stereogenic carbon in 1 is retained to some extent by the control of the crystal lattice. The factors which affect the reaction of the molecular crystals were also examined. The relationship between the reactivity and the crystal structure is discussed.

引用

页码：101 / 104

页数：4

共 16 条

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