Ionization and dissociation energies of HF and DF and their bearing on D degrees(0) (F-2)

被引:56
作者
Brundle, C. R. [1 ]
机构
[1] Bell Teleephone Labs Inc, Murray Hill, NJ 07974 USA
关键词
D O I
10.1016/0009-2614(70)80171-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The high-resolution photoelectron spectra of HF and DF have been recorded. Ionization potentials to the 2(Pi) and (2)Sigma(+) states of the ion are given, together with an estimate for the dissociation limit in the (2)Sigma(+) state. The date are compared to previous results and it is suggested that a recent mass-spectrometric determination of D degrees(0) (HF) and D degrees(0)(F-2) may be in error.
引用
收藏
页码:317 / 322
页数:6
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