SURFACE-TENSION OF POLYSILANES HAVING OXYETHYLENIC SIDE-CHAINS

被引：20

作者：

OKA, K

FUJIUE, N

NAKANISHI, S

TAKATA, T

DOHMARU, T

YUAN, CH

WEST, R

机构：

[1] UNIV OSAKA PREFECTURE, COLL ENGN, DEPT APPL CHEM, SAKAI, OSAKA 593, JAPAN

[2] UNIV WISCONSIN, DEPT CHEM, MADISON, WI 53706 USA

来源：

CHEMISTRY LETTERS | 1995年 / 10期

关键词：

D O I：

10.1246/cl.1995.875

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polysilanes having oxyethylenic side chains, {CH3-Si-CH2CH2CH2O(CH2CH2O)(m)R(1)}, where (m = 0,1,2,3) and R(1) = CH3 and C2H5, have been prepared. A polysilane of m = 3 and R = CH3 is soluble in alcohols, acetonitrile, and water. Surface tensions of these polysilanes are larger than those of the polysilanes ever reported. While dispersion component stays almost constant (ca. 30-40 dyn/cm), polar component increases with increasing oxygen atom numbers in the side chain. Copolymers also keep the high values of surface tension.

引用

页码：875 / 876

页数：2