FUNCTIONALIZATION OF C-60 BUCKMINSTERFULLERENE BY [8+2] CYCLOADDITION - SPECTROSCOPIC AND ELECTRON-TRANSFER PROPERTIES OF A TETRAHYDROAZULENOFULLERENE

被引:39
作者
BEER, E [1 ]
FEUERER, M [1 ]
KNORR, A [1 ]
MIRLACH, A [1 ]
DAUB, J [1 ]
机构
[1] UNIV REGENSBURG,INST ORGAN CHEM,D-93040 REGENSBURG,GERMANY
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 10期
关键词
D O I
10.1002/anie.199410871
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The novel C60 cycloadduct 1 is formed in the reaction of 8‐methoxyheptafulvene with buckminster‐fullerene C60. Compound 1 can be reduced to its tetraanion in four reversible steps; the spectral properties of the radical anion, dianion, and trianion were examined by UV/VIS/NIR spectroelectro‐chemistry. Adduct 1 may lead to other functional‐ized fullerenes having substructures with electron‐transfer properties. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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收藏
页码:1087 / 1089
页数:3
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