PREPARATION OF VOLATILE, MONOMERIC COPPER(I) BETA-DIKETONATE COMPLEXES

被引：41

作者：

SHIN, HK

HAMPDENSMITH, MJ

DUESLER, EN

KODAS, TT

机构：

[1] UNIV NEW MEXICO,CTR MICROENGINEERED CERAM,DEPT CHEM,ALBUQUERQUE,NM 87131

[2] UNIV NEW MEXICO,CTR MICROENGINEERED CERAM,DEPT CHEM ENGN,ALBUQUERQUE,NM 87131

来源：

POLYHEDRON | 1991年 / 10卷 / 06期

关键词：

D O I：

10.1016/S0277-5387(00)83624-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of (beta-diketonate)Cu(PMe3), where beta-diketonate = acetylacetonate (acac) (1), trifluoroacetylacetonate (2) and hexafluoroacetylacetonate (3), compounds have been prepared by the reaction of beta-diketones with (eta-5-C5H5)CuPMe3. A single crystal X-ray diffraction study of (tfa)CuPMe3 reveals that it is monomeric in the solid state with a trigonal planar copper coordination environment. All three new compounds are volatile and soluble in hydrocarbon solvents.

引用

页码：645 / 647

页数：3

共 15 条

[1]

BERRY AD, 1990, J MATER RES, V5, P1109

[2]

COLTON FA, 1988, ADV INORG CHEM RAD, P477

[3] ALKENE AND CARBON-MONOXIDE DERIVATIVES OF COPPER(I) AND SILVER(I) BETA-DIKETONATES [J].