HIGHLY SELECTIVE ASYMMETRIC HYDROLYSIS OF 2,2-DISUBSTITUTED EPOXIDES USING LYOPHILIZED CELLS OF RHODOCOCCUS SP NCIMB-11216

被引:26
作者
WANDEL, U [1 ]
MISCHITZ, M [1 ]
KROUTIL, W [1 ]
FABER, K [1 ]
机构
[1] GRAZ UNIV TECHNOL,INST ORGAN CHEM,A-8010 GRAZ,AUSTRIA
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 07期
关键词
D O I
10.1039/p19950000735
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
(+/-)-2-Methyl-2-alkyl epoxides have been resolved by biocatalytic hydrolysis employing lyophilized cells of Rhodococcus sp. NCIMB 11216. The reaction has been shown to proceed with retention of configuration leading to (S)-1,2-diols and (R)-epoxides with excellent selectivities(E > 100).
引用
收藏
页码:735 / 736
页数:2
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