RELATIONSHIP BETWEEN UNIMOLECULAR LIFETIME AND RELATIVE TRANSLATIONAL ENERGY-DISTRIBUTIONS

被引：22

作者：

HASE, WL

机构：

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 67卷 / 2-3期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(79)85159-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Relative translational energies are computed for HCCCl decomposition using classical trajectories. It is found that excited molecules with non-RRKM lifetime distributions dissociate to products with RRKM translational energy distributions. This result suggests that statistical relative translational energy distributions do not necessarily imply complete intramolecular vibrational energy redistribution. © 1979.

引用

页码：263 / 266

页数：4

共 16 条

[11]

MAYER TM, 1975, BER BUNSEN PHYS CHEM, V79, P353

[12] MOLECULAR-BEAM KINETICS - 4-ATOM COLLISION COMPLEXES IN EXCHANGE-REACTIONS OF CSCL WITH KCL AND KI [J].